Spin control: New technique sorts nanotubes by length

Caption: In a schematic of NIST's length separation technique for carbon nanotubes (l.), the nanotubes start at the bottom of a dense fluid. When spun in a centrifuge, the nanotubes begin to migrate through the fluid driven by their buoyancy, but the longer ones move faster, spreading them out by length. Photos (r.) shows a typical sample at the start and after 94 hours of spinning at 1257 radians per second (roughly 12,000 RPM). Credit: NIST. Usage Restrictions: None.

Researchers at the National Institute of Standards and Technology (NIST) have reported* a new technique to sort batches of carbon nanotubes by length using high-speed centrifuges. Many potential applications for carbon nanotubes depend on the lengths of these microscopic cylinders, and one of the most important features of the new technique, say the scientists, is that it should be easily scalable to produce industrial quantities of high-quality nanotubes.

So-called single wall carbon nanotubes (SWCNTs) are essentially sheets of carbon atoms only one atom thick that have rolled themselves into tubes with a diameter of approximately one nanometer. They have unique combinations of thermal, mechanical, optical and electronic properties that suggest a wide variety of uses, including circuit elements in molecular electronics, fluorescent tags for diagnostic and therapeutic applications in medicine and light sources for compact, efficient flat-panel displays, among many others.

Unfortunately, the methods for manufacturing carbon nanotubes always create a large percentage of nanojunk in the mix—clumps of carbon, ordinary soot, particles of metal used as a catalyst—and nanotubes come in an enormous range of lengths, from a few tens or hundreds, up to thousands of nanometers. Refining the lot is essential for most uses. For many potential applications, nanotubes need to be separated by length. In biomedical applications, for example, it has been shown that whether or not nanotubes are taken up in cells depends critically on length (see “Study: Cells Selectively Absorb Short Nanotubes.”) Nanotubes used as components in future microcircuits obviously need to fit in place, and in optical applications, a nanotube’s length determines how strongly it will absorb or emit light (see “Longer is Better for Nanotube Optical Properties.”)

In 2006, researchers found that you could separate nanotubes by “chirality” (a measure of the twist in the carbon atom sheet) by spinning them in a dense fluid in an ultracentrifuge tube because of a relationship between chirality and buoyancy. In this new work, a team of NIST researchers demonstrated that a variation of the same technique can separate nanotubes by length. They showed that while the nanotubes ultimately will move to a point of equilibrium in the centrifuge tube dictated by their buoyancy, due to friction they will move at different rates depending on their lengths.

“When we spin the centrifuge, it turns out that the longer ones move faster. We basically just run a race and the longer ones move farther in the same amount of time,” says researcher Jeffrey Fagan, “Eventually they get separated enough in position that we can just pull off layers and get different lengths.”

What’s particularly exciting, they say, is that while other techniques have been shown to sort nanotubes by length, this is the first approach that could be scaled up to produce commercially important quantities of nanotubes in a given length range. The process also removes much of unwanted junk—particularly metal particles—from the batch. NIST has applied for a patent on the process. ###

* J.A. Fagan, M.L. Becker, J. Chun and E.K. Hobbie. Length fractionation of carbon nanotubes using centrifugation. Advanced Materials. 2008. 20. 1609–1613.

Contact: Michael Baum michael.baum@nist.gov 301-975-2763 National Institute of Standards and Technology (NIST)