When an atom or molecule is deposited onto the carbon nanotube, the tube's resonant frequency changes in proportion to the mass of the atom or molecule, much like the added mass of a diver changes the flexural resonance frequency of a diving board. Measuring this change in frequency reveals the mass of the impinging atom or molecule.
"Getting nanotubes to vibrate is fairly easy," said Jensen. "The difficult part is detecting those small vibrations. We accomplished this by field-emitting, or spraying, electrons from the tip of the nanotube and detecting the resulting electrical current."
Using their NEMS mass sensor, Zettl, Jensen and Kim were able to weigh individual gold atoms and measure masses as small as two fifths that of a gold atom at room temperature and in just a little more than one second of time. A gold atom has a mass of 3.25 x 10-25 kilograms, which means that there are about 3 million million million million gold atoms in a single kilogram.
While there have been other NEMS that function as mass sensors before, most of these previous devices were fashioned from silicon, and none had achieved the magical single-atom resolution at room temperature. The carbon nanotube mass sensor of Zettl's group is a thousand times smaller by volume than typical NEMS resonators – measuring only about a billionth of a meter in diameter and 200 billionths of a meter in length.
"Carbon nanotubes are the ideal material for this purpose and their small size makes them sensitive enough to resolve single atoms even at room temperature," Jensen said.
While scientists already have the ability to measure the mass of individual atoms through a complex technique known as mass spectrometry, this new carbon nanotube NEMS mass sensor offers some distinct advantages and opens the door to new possibilities, as Jensen explained.
"Unlike mass spectrometry, our device does not require the ionization of neutral atoms or molecules that can destroy samples such as proteins. Also unlike mass spectrometers, our carbon nanotube mass sensor becomes more sensitive at higher mass ranges, which makes it more suitable for measuring large biomolecules like DNA. Finally, our device is small enough so that, in time, it could be incorporated onto a chip." ###
Zettl, Jensen and Kim described their NEMS mass sensor in a paper published in the journal Nature Nanotechnology, entitled: "An atomic-resolution nanomechanical mass sensor." This research was supported by the U.S. Department of Energy's Office of Science, Basic Energy Sciences Program's Materials Sciences and Engineering Division, and by the National Science Foundation within the Center of Integrated Nanomechanical Systems.
Contact: Lynn Yarris email@example.com 510-486-5375 DOE/Lawrence Berkeley National Laboratory
Tags: Nano or Nanotechnology and Nanotech